Monday, August 10, 2015

Moseley

An early physics pioneer you rarely hear about is Henry Moseley, who died 100 years ago today. Moseley made an important discovery now called "Moseley's Law."

Up until Moseley's time, chemical elements in the iconic Periodic Table were arranged according to weight. There was other rhyme and reason to the arrangement of elements in the Table, but no true understanding of their masses beyond: things get heavier. There was hope that atomic mass would reveal something fundamental about physics, and the 1914 Nobel Prize went to Harvard's T. W. Richards for his careful and methodical measurements of atomic weights.

Moseley showed that by shining X-rays onto atomic samples, he got a distinct integer value for each element which he called Z. Others before Moseley -- namely Bunsen and Kirchoff -- had shown how unseen atoms could be "seen" and identified by burning them in flames, but Moseley's experiments were beautifully simple and related all elements together with their Z-values instead of getting a unique "fingerprint" for each. Moseley's law is still used to identify elements in deep space.

Exactly what Z was had only been postulated a few years earlier. Niels Bohr had shown that Z was the nuclear charge (1 for the hydrogen atom) and Ernest Rutherford had suggested that Z for heavy atoms might be about half an element's atomic weight. A Dutchman, Antonius van den Broek had suggested that Z was an element's "atomic number" and Moseley proved it.

Good ideas need good proof to be good science.

The Periodic Table was never the same after Moseley.

Henry Moseley probably should have gotten the 1915 or 1916 Nobel Prize in Physics, but he was killed by a Turkish bullet at Gallipoli at age 27.   
Henry Moseley (1887-1915)
Isaac Asimov wrote: "In view of what he [Moseley] might still have accomplished ... his death might well have been the most costly single death of the War to mankind generally."

5 comments:

ndspinelli said...

"HANDS UP!" Sorry, wrong anniversary.

Rabel said...

"his death might well have been the most costly single death of the War to mankind generally"

Or his continued work could have advanced nuclear physics more rapidly and the bomb could have been in Hitler's hands before WW2. You never know what's gonna happen.

William said...

I blame Churchill......What's the name of that brilliant German chemist who invented poison gas? He wanted to win WWI for the Germans and demonstrate to the Kaiser that German Jews were just as patriotic and useful as other Germans. I wonder if he lived long enough to see the full fruition of his ideas.

ricpic said...

I loved fiddling with the Bunsen Burner in lab class. And yes, I understand fiddling is not scientific terminology.

chickelit said...

@William: you must thinking Fritz Haber. He won the 1918 Nobel for inventing a way to make fertilizer from thin air. After the war, he tried pay off Germany's crushing war debt by extracting gold from sea water. He escaped to England after the rise of the Third Reich,